IUPAC > Gold Book > alphabetical index > R > repulsive potential-energy surface
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repulsive potential-energy surface
A surface for an exergonic reaction A + BC in which the col corresponds to considerable separation between the products A–B + C . The energy barrier in the potential-energy profile is in the later stages of the reaction path. On such a surface most of the energy is released after A–B is formed. Repulsive surfaces are also called late-downhill surfaces, and the barrier in such a surface is called a Type-II barrier.
Source:
PAC, 1996, 68, 149 (A glossary of terms used in chemical kinetics, including reaction dynamics (IUPAC Recommendations 1996)) on page 185
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Cite as: IUPAC Compendium of Chemical Terminology, Electronic version, http://goldbook.iupac.org/R05306.html.
Transformed and rewritten from PDF version (entry http://www.iupac.org/goldbook/R05306.pdf)
by: Miloslav Nic, Jiri Jirat, Bedrich Kosata, ICT Prague, Czech Republic
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