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residual liquid junction (potential) error

in pH measurement
Error arising from breakdown in the assumption that the liquid junction potential remains constant when solution X is substituted for solution S in the operational cell.
Source:
PAC, 1985, 57, 531 (Definition of pH scales, standard reference values, measurement of pH and related terminology (Recommendations 1984)) on page 541
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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.R05313.
Original PDF version: http://www.iupac.org/goldbook/R05313.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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