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rigid chain

The rod-like chain of an MCPLC (main-chain polymer liquid crystal) with direct links between the mesogenic groups for which the persistence length is at least comparable with the contour length and much greater than the diameter.
Source:
PAC, 2002, 74, 493 (Definitions of basic terms relating to polymer liquid crystals(IUPAC Recommendations 2001)) on page 505
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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2009-09-07; version: 2.1.5.
DOI of this term: doi:10.1351/goldbook.RT06871.
Original PDF version: http://www.iupac.org/goldbook/RT06871.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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