IUPAC > Gold Book > alphabetical index > S > second-order transition
icon


Indexes

second-order transition
A transition in which a crystal structure undergoes a continuous change and in which the first derivatives of the Gibbs energies (or chemical potentials) are continuous but the second derivatives with respect to temperature and pressure (i.e. heat capacity, thermal expansion, compressibility) are discontinuous. Example: The order-disorder transition in metal alloys, for example, CuZn. Synonymous with continuous transition.
Source:
PAC, 1994, 66, 577 (Definitions of terms relating to phase transitions of the solid state (IUPAC Recommendations 1994)) on page 589
Interactive Link Maps
First LevelSecond LevelThird Level
GraphGraphGraph
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2008-10-07; version: 2.0.2.
DOI of this term: doi:10.1351/goldbook.S05531.
Original PDF version (may be out of date): http://www.iupac.org/goldbook/S05531.pdf.
Version for print | History of this term
picture