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SM-interference

Interference by a substance that produces a signal by a similar mechanism to the analyte, which in the given procedure (including the apparatus used) can not be distinguished from the signal given by the analyte. For example, in a colour reaction with an organic ligand by also reacting with the ligand and producing a coloured compound absorbing at the same wavelength as the compound produced by the analyte or in an atomic spectrochemical analysis by absorbing or emitting at the same wavelength as the analyte.
Source:
PAC, 1983, 55, 553 (Recommendations for the usage of selective, selectivity and related terms in analytical chemistry) on page 554
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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.S05715.
Original PDF version: http://www.iupac.org/goldbook/S05715.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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