Interference due to changes in the
volatilization rate of the dry
aerosol particles in the case when
volatilization of the analyte is incomplete in the presence and/or absence of the concomitant. This interference can either be specific, if the analyte and interferent form a new phase of different thermostability, as when
Mg and
Al form
MgAl2O4
in an air–acetylene flame, or non-specific, if the analyte is simply dispersed in a large excess of the interferent, as when
Ag is dispersed in
ThO2.
If the interferent has a high boiling point, this latter is sometimes referred to as a blocking interference. It is often difficult to make sharp distinctions between the specific and non-specific solute-
volatilization interferences.
Source:
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
doi:10.1351/goldbook.