IUPAC > Gold Book > alphabetical index > S > solvolysis



Also contains definition of: alcoholysis

Generally, reaction with a solvent, or with a lyonium ion or lyate ion involving the rupture of one or more bonds in the reacting solute. More specifically the term is used for substitution elimination and fragmentation reactions in which a solvent species is the nucleophile ('alcoholysis' if the solvent is an alcohol, etc.).
PAC, 1994, 66, 1077 (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1165
Interactive Link Maps
First LevelSecond LevelThird Level
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.S05762.
Original PDF version: http://www.iupac.org/goldbook/S05762.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
Current PDF version | Version for print | History of this term