The term refers to the relationship between the amounts of substances that react together in a particular chemical reaction, and the amounts of products that are formed. The general
stoichiometric equation:
provides the information that
a moles of A reacts with
b moles of B to produce
y moles of Y and
z moles of Z. The stoichiometry of a reaction may be unknown, or may be very complex. For example, the thermal
decomposition of acetaldehyde yields mainly methane and carbon monoxide, but also a variety of minor products such as ethane, acetone and diacetyl. The
stoichiometric equation:
is therefore only an approximate one. Even when the overall stoichiometry of a reaction is well defined, it may be time-dependent in that it varies during the course of a reaction. Thus if a reaction occurs by the mechanism

,
and X is formed in substantial amounts during the course of the process, the relationship between the amounts of A, X and Y will vary with time, and no one
stoichiometric equation can represent the reaction at all times.
Source:
PAC, 1996, 68, 149
(A glossary of terms used in chemical kinetics, including reaction dynamics (IUPAC Recommendations 1996))
on page 187
InChI=1/C2H4O/c1-2-3/h2H,1H3
IKHGUXGNUITLKF-UHFFFAOYAB
InChI=1/CH4/h1H4
VNWKTOKETHGBQD-UHFFFAOYAM
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
doi:10.1351/goldbook.