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superequivalent adsorption

This occurs when the specifically adsorbed amount of charge in the inner Helmholtz plane is higher than the charge on the metal phase, taken with the reverse sign.
Source:
PAC, 1986, 58, 437 (Interphases in systems of conducting phases (Recommendations 1985)) on page 448
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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.S06140.
Original PDF version: http://www.iupac.org/goldbook/S06140.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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