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umpire sample

A sample taken, prepared and stored in an agreed upon manner for the purpose of settling a dispute. The agreement usually extends beyond the sample to the basis for reaching a decision (e.g. quantity of material from which taken, use of a third party and criteria serving as the basis for acceptance, rejection or economic adjustment). The term 'reference sample' has been used in this context but this term more properly should be used in conjunction with a 'reference material' or 'reference standard' which has a true or assigned value for a constituent or property. One of the characteristics of a reference material or reference standard is that it must have a negligible sampling error between test portions.
PAC, 1990, 62, 1193 (Nomenclature for sampling in analytical chemistry (Recommendations 1990)) on page 1203
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.U06550.
Original PDF version: http://www.iupac.org/goldbook/U06550.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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