If the temperature
coefficient of the rate of
adsorption is very small, the adsorption process is said to be unactivated (i.e. to have a negligible
activation energy). In this case the
sticking coefficient at low coverages may be near unity particularly for smaller molecules.
Source:
PAC, 1976, 46, 71
(Manual of Symbols and Terminology for Physicochemical Quantities and Units - Appendix II. Definitions, Terminology and Symbols in Colloid and Surface Chemistry. Part II: Heterogeneous Catalysis)
on page 79
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
doi:10.1351/goldbook.
