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Yukawa–Tsuno equation

A multiparameter extension of the Hammett equation to quantify the role of enhanced resonance effects on the reactivity of meta- and para-substituted benzene derivatives, e.g.
log 10 k = log 10 k 0 + ρ [ σ + r ( σ + − σ ) ]
The parameter r gives the enhanced resonance effect on the scale (σ + – σ) or (σ – σ), respectively.
Source:
PAC, 1994, 66, 1077 (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1176
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.Y06734.
Original PDF version: http://www.iupac.org/goldbook/Y06734.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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