The property of surface activity is usually due to the fact that the molecules of
the substance are amphipathic or amphiphilic
, meaning that each contains both a hydrophilic
and a hydrophobic (lipophilic
) group. This assumes that one of the two phases is aqueous, and the other non-aqueous.
If both are non-aqueous (e.g. oil/air), molecules containing organophilic and organophobic
groups may be amphipathic and surface active.
PAC, 1972, 31, 577
(Manual of Symbols and Terminology for Physicochemical Quantities and Units, Appendix
II: Definitions, Terminology and Symbols in Colloid and Surface Chemistry)
on page 612
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by
A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997).
XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic,
J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook