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Archibald's method

A sedimentation method based on the fact that at the meniscus and at the bottom of the centrifuge cell there is never a flux of the solute across a plane perpendicular to the radial direction and the equations characterizing the sedimentation equilibrium always apply there, even though the system as a whole may be far from equilibrium. The use of the term 'approach to sedimentation equilibrium' for Archibald's method is discouraged, since it has a more general meaning.
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.A00428.
Original PDF version: http://www.iupac.org/goldbook/A00428.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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