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atom-atom polarizability

A quantity used in perturbation HMO theory as a measure of the change in electron density, q, of atom s caused by a change in the electronegativity (or Coulomb integral) of atom r:
π sr = ∂ q s ∂ a r
PAC, 1999, 71, 1919 (Glossary of terms used in theoretical organic chemistry) on page 1924
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
Last update: 2014-02-24; version: 2.3.3.
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