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Baldwin's rules

A set of empirical rules for certain formations of 3- to 7-membered rings. The predicted pathways are those in which the length and nature of the linking chain enables the terminal atoms to achieve the proper geometries for reaction. The disfavoured cases are subject to severe distortions of bond angles and bond distances.
Source:
PAC, 1994, 66, 1077 (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1088
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.B00592.
Original PDF version: http://www.iupac.org/goldbook/B00592.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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