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calorimetric titration

A titration performed in a calorimeter which produces a plot of heat change versus volume of titrant. This is the preferred term for experiments in which the main goal is the measurement of thermodynamic parameters. Because such experiments may be performed in any of a variety of types of calorimeters with varying degrees of calorimetric accuracy, it is important that the reporting of such results include an assessment of accuracy and precision. The term stands in contrast to the main emphasis in enthalpimetric analysis.
Source:
PAC, 1994, 66, 2487 (Nomenclature of thermometric and enthalpimetric methods in chemical analysis (IUPAC Recommendations 1994)) on page 2490
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.C00785.
Original PDF version: http://www.iupac.org/goldbook/C00785.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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