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The centre of a Mössbauer spectrum is defined as the Doppler-velocity at which the resonance maximum is (or would be) observed when all magnetic dipole, electric quadrupole, etc. hyperfine interactions are (or would be) absent. The contribution of the second order Doppler shift (δ T) should be indicated, if possible.
Source:
PAC, 1976, 45, 211 (Nomenclature and Conventions for Reporting Mossbauer Spectroscopic Data) on page 215
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: https://doi.org/10.1351/goldbook.C00931.
Original PDF version: http://www.iupac.org/goldbook/C00931.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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