Goldbook title
IUPAC > Gold Book > alphabetical index > C > crystal field
Gold G Icon
Indexes Download

The average static electric field experienced by an ion, molecule or atom in a crystal generated by all the other surrounding atoms, molecules, or ions. The concept introduced by Becquerel and developed by Bethe has been extended to refer to the field generated by the ligands (anions or neutral species) surrounding a transition metal ion in a coordination compound. With the understatement that some covalency may exist in the metal-ligand bond, it is often referred to as ligand field.
Source:
PAC, 1999, 71, 1919 (Glossary of terms used in theoretical organic chemistry) on page 1932
Interactive Link Maps
First Level Second Level Third Level
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook.
Last update: 2008-10-07; version: 2.0.2.
DOI of this term: https://doi.org/10.1351/goldbook.CT06770.
Original PDF version (may be out of date): http://www.iupac.org/goldbook/CT06770.pdf.
Version for print | History of this term
picture