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gel

Non-fluid colloidal network or polymer network that is expanded throughout its whole volume by a fluid.
Notes:
  1. A gel has a finite, usually rather small, yield stress.
  2. A gel can contain:
    1. a covalent polymer network, e.g., a network formed by crosslinking polymer chains or by non-linear polymerization;
    2. a polymer network formed through the physical aggregation of polymer chains, caused by hydrogen bonds, crystallization, helix formation, complexation, etc, that results in regions of local order acting as the network junction points. The resulting swollen network may be termed a thermoreversible gel if the regions of local order are thermally reversible;
    3. a polymer network formed through glassy junction points, e.g., one based on block copolymers. If the junction points are thermally reversible glassy domains, the resulting swollen network may also be termed a thermoreversible gel;
    4. lamellar structures including mesophases, e.g., soap gels, phospholipids and clays;
    5. particulate disordered structures, e.g., a flocculent precipitate usually consisting of particles with large geometrical anisotropy, such as in V2O5 gels and globular or fibrillar protein gels.
  3. Corrected from previous definition where the definition is via the property identified in Note 1 (above) rather than of the structural characteristics that describe a gel.
Source:
PAC, 2007, 79, 1801 (Definitions of terms relating to the structure and processing of sols, gels, networks, and inorganic-organic hybrid materials (IUPAC Recommendations 2007)) on page 1806
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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.G02600.
Original PDF version: http://www.iupac.org/goldbook/G02600.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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