Reaction, generally reversible, that involves the penetration
of a host material by guest
species without causing a major structural modification of the host.
- Intercalation can refer to the insertion of a guest species into a one-, two- or three-dimensional host structure.
- The guest species is not distributed randomly but occupies positions
predetermined by the structure of the host material.
- Examples of intercalation reactions are the insertion of lithium into layered
(0 ≤ x ≤ 1)]
and of potassium into the layers of graphite
PAC, 2007, 79, 1801
(Definitions of terms relating to the structure and processing of sols, gels, networks,
and inorganic-organic hybrid materials (IUPAC Recommendations 2007))
on page 1823
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by
A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997).
XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic,
J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook