The bond between atoms with sharply different electronegativities. In strict terms,
an ionic bond refers to the electrostatic attraction experienced between the electric
charges of a cation
and an anion
, in contrast with a purely covalent bond
. In practice, it is preferable to consider the amount of ionic character of a bond
rather than referring to purely ionic or purely covalent bonds. The relationship was
proposed (L. Pauling) for the estimation of ionic character of a bond between atoms
A and B:
are the Pauling electronegativities
of atoms A and B. This type of bonding is realized mostly in solids.
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by
A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997).
XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic,
J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook