Lifetime of a molecular entity, which decays by first-order kinetics, is the time
needed for a concentration of the entity to decrease to
of its original value, i.e.,
Statistically, it represents the life expectation of the entity. It is equal to the
reciprocal of the sum of the first-order rate constants of all processes causing the
decay of the molecular entity.
the first-order rate constants for all decay processes of the decaying state.
Lifetime is used sometimes for processes, which are not first order. However, in such
cases, the lifetime depends on the initial concentration of the entity, or of a quencher and, therefore, only an initial or a mean lifetime can be defined. In this case it
should be called decay time.
Occasionally, the term half-life
is used, representing the time needed for the concentration of an entity to decrease
to one half of its original value, i.e.,
For first-order reactions,
PAC, 2007, 79, 293
(Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006))
on page 363
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by
A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997).
XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic,
J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook