A molecule of high relative molecular mass
, the structure of which essentially comprises the multiple repetition of units derived,
actually or conceptually, from molecules of low relative molecular mass
In many cases, especially for synthetic polymers, a molecule can be regarded as having
a high relative molecular mass if the addition or removal of one or a few of the units has a negligible effect on
the molecular properties. This statement fails in the case of certain macromolecules
for which the properties may be critically dependent on fine details of the molecular
If a part or the whole of the molecule has a high relative molecular mass and essentially comprises the multiple repetition of units derived, actually or conceptually,
from molecules of low relative molecular mass, it may be described as either macromolecular or polymeric, or by polymer used adjectivally.
PAC, 1996, 68, 2287
(Glossary of basic terms in polymer science (IUPAC Recommendations 1996))
on page 2289
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by
A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997).
XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic,
J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook