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martensitic transition

A diffusionless transition (first studied in the steel alloy, Martensite), at constant composition, generated by coordinated atomic, ionic or molecular displacements over distances smaller than interatomic distances in the parent phase. The cooperative rearrangements of the crystal structure generally take place progressively by the movement of a two-dimensional interface through the solid. Examples: The face-centred-cubic to body-centred-tetragonal transition of iron containing some carbon; the transition of tetragonal ZrO2 to monoclinic ZrO2 .
Source:
PAC, 1994, 66, 577 (Definitions of terms relating to phase transitions of the solid state (IUPAC Recommendations 1994)) on page 585
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.M03708.
Original PDF version: http://www.iupac.org/goldbook/M03708.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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