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Photoinduced extrusion of carbon monoxide (CO).
  1. Typical example is the Norrish Type I photoreaction, in which, after production of the diradical upon photoinduced α-cleavage, CO is eliminated. This reaction has been widely exploited for the production of radicals in crystals, as well as for the synthesis of cyclic compounds.
  2. Another example is the photodecarbonylation of alpha-aryl aldehydes.
PAC, 2007, 79, 293 (Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)) on page 388
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
Last update: 2014-02-24; version: 2.3.3.
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