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quadrupole splitting

in Mössbauer spectroscopy
The measured Doppler velocity difference between the two peaks seen in quadrupole split spectra from nuclides such as 57Fe and 119Sn.
Source:
PAC, 1976, 45, 211 (Nomenclature and Conventions for Reporting Mossbauer Spectroscopic Data) on page 214
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.Q04972.
Original PDF version: http://www.iupac.org/goldbook/Q04972.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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