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residual emission anisotropy

Photoselected molecules hindered in their rotation (e.g., in lipid bilayers or liquid crystals) do not become randomly oriented even after long time periods. Thus, the emission anisotropy does not decay to zero but to a steady value, r ∞, called residual emission anisotropy. In the case of a single rotational correlation time, τ c or θ, the decay of emission anisotropy following δ-pulse excitation is given by:
r t = ( r 0 − r ∞ ) exp ( − t τ c ) + r ∞
where r 0 is the fundamental emission anisotropy.
Note:
The term residual anisotropy is to be preferred to 'limiting anisotropy'.
Source:
PAC, 2007, 79, 293 (Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)) on page 414
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.RT07473.
Original PDF version: http://www.iupac.org/goldbook/RT07473.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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