A reaction intermediate
in which the bond arrangement around an initially double-bonded carbon atom (typically
a carbonyl carbon atom) has been transformed from trigonal to tetrahedral. For example,
aldol in the condensation reaction
of acetaldehyde (but most tetrahedral intermediates have a more fleeting existence).
PAC, 1994, 66, 1077
(Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994))
on page 1173
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by
A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997).
XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic,
J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook