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time-dependent stoichiometry

A state in which if intermediates are formed in significant amounts during the course of a reaction, the overall stoichiometric equation does not apply throughout.
Source:
PAC, 1981, 53, 753 (Symbolism and terminology in chemical kinetics (Provisional)) on page 754
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.T06378.
Original PDF version: http://www.iupac.org/goldbook/T06378.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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