https://doi.org/10.1351/goldbook.TT06926
The sum of @ET06925@, \(\nu_{\text{ep}}\), of an ion and the electroosmotic velocity, \(\nu _{\text{eo}}\). \[\nu_{\text{tot}} = \nu_{\text{ep}}\,+\,\nu_{\text{eo}}\] This quantity can be measured experimentally as the effective length of the capillary divided by the @MT06924@ (\(L_{\text{eff}}/t_{\text{m}}\)).
Notes:
- Depending on the signs and relative magnitudes of these velocities, the total velocity of an analyte can have either the same or the opposite direction to the electroosmotic velocity.
- The total velocity is the velocity of the ion measured as a displacement relative to the capillary wall divided by time.