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The term designates structures in which a hydrogen atom is bonded to both a carbon atom and a metal atom. The term is also used to characterize the interaction between a CH bond and an unsaturated metal centre, and to describe similar bonding of a transition metal with Si–H compounds. The expression 'µ-hydrido-bridged' is also used to describe the bridging hydrogen.
PAC, 1994, 66, 1077 (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1082
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
Last update: 2014-02-24; version: 2.3.3.
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