When the addition of a differential amount
is effected at constant gas volume, the differential molar energy of adsorption of
is defined as:
where the differential molar surface excess energy,
, is given by
and the differential molar interfacial energy,
is the differential molar energy of component
in the gas phase, i.e.
PAC, 1972, 31, 577
(Manual of Symbols and Terminology for Physicochemical Quantities and Units, Appendix
II: Definitions, Terminology and Symbols in Colloid and Surface Chemistry)
on page 603
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by
A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997).
XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic,
J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook