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mass-transfer-controlled electrolyte rate constant

In controlled-potential coulometry and related techniques, the empirically evaluated constant of proportionality defined by the equation
s B = − 1 c B d c B d t
where c B is the bulk concentration of the substance B, and d c B d t is the rate of change of that concentration, resulting from the consumption of B by reduction or oxidation at the working electrode.
PAC, 1985, 57, 1491 (Recommended terms, symbols, and definitions for electroanalytical chemistry (Recommendations 1985)) on page 1501
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
Last update: 2014-02-24; version: 2.3.3.
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