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non-ideal, non-linear chromatography

Chromatographic process, where both isotherm curvature and other peak-broadening processes (such as diffusion) contribute to the peak shape.
This case comprises most peaks in common practice that are characterised as 'tailing' or 'fronting'.
PAC, 1996, 68, 1591 (Nomenclature for non-linear chromatography (IUPAC Recommendations 1996)) on page 1594
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
Last update: 2014-02-24; version: 2.3.3.
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