An electronic transition in which a large fraction of an electronic charge is transferred from one region of a molecular entity, called the electron donor, to another, called the electron acceptor (intramolecular CT
) or from one molecular entity to another (intermolecular CT
). Typical for donor-acceptor complexes or multichromophoric molecular entities. In some cases the charge-transfer absorption band may be obscured by the absorption of the partners.
PAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2232 (https://doi.org/10.1351/pac199668122223)