pericyclic reaction
A chemical reaction in which concerted reorganization of bonding takes place throughout a cyclic array of continuously bonded atoms. It may be viewed as a reaction proceeding through a fully conjugated cyclic transition state. The number of atoms in the cyclic array is usually six, but other numbers are also possible. The term embraces a variety of processes, including cycloadditions, cheletropic reactions, electrocyclic reactions, sigmatropic rearrangements, etc. (provided they are concerted).
See also: multi-centre reaction
PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1150 (