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Esin and Markov coefficient

The left-hand side of one of the various cross-differential relationships that can be obtained from the Gibbs adsorption equation when only one chemical potential (μ) is considered as variable, viz.
( ∂ E ∂ μ ) T , p , σ = − ( ∂ Γ ∂ σ ) T , p , μ
where E is the potential difference, T is the temperature, p is the pressure, Γ is the surface excess and σ is the charge density.
Source:
PAC, 1986, 58, 437 (Interphases in systems of conducting phases (Recommendations 1985)) on page 446
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.E02218.
Original PDF version: http://www.iupac.org/goldbook/E02218.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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