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ketyls
Radical anions (or the corresponding salts) derived from ketones by addition of an electron R2C.–O mesomer-arrow R2C–O..
Note:
Ketyls produce two types of conjugate acids: R2C.–OH and R2CH–O.. The former are α-hydroxyalkyl radicals and the latter are alkoxyl radicals, but they have also been called ketyls in photochemistry.
Source:
PAC, 1995, 67, 1307 (Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)) on page 1346
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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2008-09-12; version: 2.0.1.
DOI of this term: doi:10.1351/goldbook.K03389.
Original PDF version (may be out of date): http://www.iupac.org/goldbook/K03389.pdf.
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