aminoxyl radicals

https://doi.org/10.1351/goldbook.A00285
Compounds having the structure R2N–O·\(\leftrightarrow\) R2N·+–O−; they are @[email protected] derived from @[email protected] by removal of the hydrogen atom from the hydroxy group, and are in many cases isolable. The synonymous terms '@[email protected]' and '@[email protected]' erroneously suggest the presence of a nitro group; their use is not desirable. E.g.
(ClCH2)2N–O·
bis(chloromethyl)aminoxyl.
Source:
PAC, 1995, 67, 1307. (Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)) on page 1317 [Terms] [Paper]
See also:
PAC, 1993, 65, 1357. (Revised nomenclature for radicals, ions, radical ions and related species (IUPAC Recommendations 1993)) on page 1357 [Terms] [Paper]
Cite as: IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). Online version (2019-) created by S. J. Chalk. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook.
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Last revised: February 24, 2014