A @[email protected] for a process A + B–C in which the initial descent of the system into the product valley is associated with a substantial decrease in the A–B distance and with little separation between the products A–B and C. In terms of a @[email protected], the energy barrier occurs in the early stage of the @[email protected] Attractive surfaces are also called early-downhill surfaces, and the barrier in such a surface is called a Type-I barrier.
PAC, 1996, 68, 149. (A glossary of terms used in chemical kinetics, including reaction dynamics (IUPAC Recommendations 1996)) on page 153 [Terms] [Paper]