captodative effect
Effect on the stability of a carbon-centred @[email protected] determined by the combined action of a captor (electron withdrawing) and a dative (electron releasing) substituent, both attached to the radical centre. The term is also used for certain unsaturated compounds.
PAC, 1994, 66, 1077. (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1092 [Terms] [Paper]