https://doi.org/10.1351/goldbook.C00963
The @[email protected], by the @[email protected] end of a growing chain-polymer, of an atom from another molecule. The growth of the polymer chain is thereby terminated but a new radical, capable of chain @[email protected] and @[email protected], is simultaneously created. For the example of alkene @[email protected] cited for a @[email protected], the reaction:
C00963-1.png
represents a chain transfer, the radical Cl3C· inducing further @[email protected]:
C00963-2.png
C00963-3.png
The phenomenon occurs also in other chain reactions such as @[email protected]
See also:
telomerization
Source:
PAC, 1994, 66, 1077. (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1094 [Terms] [Paper]