in catalysis
For the process: \[k = A\ \text{e}^{\frac{-E}{R\ T}}\] where \(k\) is a @[email protected], \(A\) the frequency factor and \(E\) the @[email protected], \(A\) and \(E\) sometimes exhibit compensation, i.e. they change in the same direction with change in @[email protected] for a given reaction or with change in reaction for a given @[email protected]
PAC, 1976, 46, 71. (Manual of Symbols and Terminology for Physicochemical Quantities and Units - Appendix II. Definitions, Terminology and Symbols in Colloid and Surface Chemistry. Part II: Heterogeneous Catalysis) on page 82 [Terms] [Paper]