## Dimroth–Reichardt ET parameter

https://doi.org/10.1351/goldbook.D01746
A measure of the @[email protected] (loosely @[email protected]) of a solvent, based on the maximum wavenumber of the longest @[email protected] electronic absorption band of:
D01746.png
in a given solvent. $$E_{\text{T}}$$, called $$E_{\text{T}}(30)$$ by its originators, is given by: $E_{\text{T}} = 2.859\times 10^{-3}\ \nu = 2.859\times 10^{4}\ \lambda ^{-1}$ where $$E_{\text{T}}$$ is in $$\text{kcal mol}^{-1}$$, $$\nu$$ is in $$\text{cm}^{-1}$$ and $$\lambda$$ is in $$\text{nm}$$. The so-called normalized $$E_{\text{T}}^{\text{N}}$$ scale is defined as: $E_{\text{T}}^{\text{N}}=\frac{E_{\text{T}}\left(\text{solvent}\right)- E_{\text{T}}\left(\text{Si}\text{Me}_{4}\right)}{E_{\text{T}}\left(\text{water}\right)- E_{\text{T}}\left(\text{Si}\text{Me}_{4}\right)}=\frac{E_{\text{T}}\left(\text{solvent}\right)- 30.7}{32.4}$