Donnan equilibrium
The equilibrium characterized by an unequal distribution of diffusible ions between two ionic solutions (one or both of the solutions may be gelled) separated by a @MT06878@ which is impermeable to at least one of the ionic species present, e.g. because they are too large to pass through the pores of the @MT06878@. The @MT06878@ may be replaced by other kinds of restraint, such as @GT07621@, the field of gravity, etc., which prevent some ionic components from moving from one phase to the other, but allow other components to do so.
PAC, 1972, 31, 577. (Manual of Symbols and Terminology for Physicochemical Quantities and Units, Appendix II: Definitions, Terminology and Symbols in Colloid and Surface Chemistry) on page 619 [Terms] [Paper]