effective molarity (effective concentration)

https://doi.org/10.1351/goldbook.E01896
The ratio of the first-order @O04322@ of an @I03130@ reaction involving two functional groups within the same @M03986@ to the second-order @O04322@ of an analogous @I03098@ @E02035@. This ratio has the dimension of concentration. The term can also apply to an @E02177@.
See also:
intramolecular catalysis
Source:
PAC, 1994, 66, 1077. (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1108 [Terms] [Paper]
Cite as: IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). Online version (2019-) created by S. J. Chalk. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook.
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Last revised: February 24, 2014