electrode reaction

https://doi.org/10.1351/goldbook.E01960
For an @[email protected] at a given potential the current is controlled by the kinetics of a number of steps which include the transport of reactants to and from the @[email protected] and the interfacial reaction itself. The latter, which is called the electrode reaction, must always include at least one elementary step in which charge is transferred from one phase to the other, but may also involve purely chemical steps within the @[email protected]
Source:
PAC, 1980, 52, 233. (Electrode Reaction Orders, Transfer Coefficients and Rate Constants. Amplification of Definitions and Recommendations for Publication of Parameters) on page 235 [Terms] [Paper]