harpoon mechanism

https://doi.org/10.1351/goldbook.H02746
Reaction @[email protected] (thermal or photoinduced) between neutral molecular or atomic entities in which long-range @[email protected] is followed by a considerable reduction of the distance between donor and acceptor sites as a result of the electrostatic attraction in the @[email protected] created.
Source:
PAC, 1996, 68, 2223. (Glossary of terms used in photochemistry (IUPAC Recommendations 1996)) on page 2245 [Terms] [Paper]
Cite as: IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). Online version (2019-) created by S. J. Chalk. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook.
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Last revised: February 24, 2014