heterolytic bond-dissociation energy

https://doi.org/10.1351/goldbook.H02810
The energy required to break a given bond of some specific compound by @[email protected] For the @[email protected] of a neutral molecule AB in the gas phase into A+ and B− the heterolytic @[email protected] D(A+B−) is the sum of the @[email protected] energy, D(A–B), and the @[email protected] @[email protected] of the radical A· minus the @[email protected] of the radical B·.
Source:
PAC, 1994, 66, 1077. (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1121 [Terms] [Paper]
Cite as: IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). Online version (2019-) created by S. J. Chalk. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook.
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Last revised: February 24, 2014