heterolytic bond-dissociation energy

https://doi.org/10.1351/goldbook.H02810
The energy required to break a given bond of some specific compound by @H02809@. For the @D01801@ of a neutral molecule AB in the gas phase into A+ and B− the heterolytic @B00699@ D(A+B−) is the sum of the @B00698@ energy, D(A–B), and the @A00141@ @I03199@ of the radical A· minus the @E01977@ of the radical B·.
Source:
PAC, 1994, 66, 1077. (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1121 [Terms] [Paper]
Cite as: IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). Online version (2019-) created by S. J. Chalk. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook.
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Last revised: February 24, 2014